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Design and Performance Evaluation of Air Sparging Trench for the
Treatment of VOCs and Arsenic (October, 2006)
Omer J. Uppal, Xpert Design and Diagnostics, LLC, 22 Marin Way, Stratham, NH
03885, Tel: 603-778-1100, Fax: 603-778-2121, Email: Uppal@xdd-llc.com
Michael C. Marley, Xpert Design and Diagnostics, LLC, 22 Marin Way, Stratham, NH
03885, Tel: 603-778-1100, Fax: 603-778-2121, Email: Marley@xdd-llc.com
Dennis Keane, Xpert Design and Diagnostics, LLC, 22 Marin Way, Stratham, NH 03885,
Tel: 603-778-1100, Fax: 603-778-2121, Email: Keane@xdd-llc.com
Dean Peschel, Project Manager, City of Dover, 288 Central Avenue, Dover, NH 03820,
Tel: 603-743-6094, Fax: 603-742-3019, Email: dean.peschel@ci.dover.nh.us
An air sparging trench alternative was compared to a capping/pump and treat remedy for
groundwater impacted with volatile organic compounds (VOCs) and arsenic constituents
of concern (COCs), as specified in a Record of Decision (ROD) at a United States
Environmental Protection Agency (USEPA) Comprehensive Environmental Response,
Compensation, and Liability Act (CERCLA) landfill site. The air sparging trench with an
engineered backfill material was designed to intercept and treat COCs migrating with
groundwater from beneath the landfill. The design and performance evaluation of the
trench are presented.
The trench was designed to provide in-situ flow-through treatment of VOCs by a
combination of volatilization and aerobic biodegradation, and arsenic by precipitation
and sorption. Various laboratory and field-scale tests were performed to evaluate the
effectiveness of the trench in removing COCs. The results of laboratory, field-scale
testing, and a stripping analysis indicated that the trench could remove the majority of
VOCs that are present at the site by air sparging. Organic compounds that are not
expected to be completely volatilized were projected to degrade by aerobic
microorganisms in the oxygenated groundwater within and down-gradient of the trench.
Geochemical modeling was performed to evaluate the ability of oxidizing conditions
within trench to remove dissolved arsenic from groundwater through co-precipitation and
sorption onto iron oxides. The modeling results indicated that oxidizing conditions
created in the trench will result in precipitation of dissolved arsenic and other reduced
minerals into the void spaces of the trench backfill material, significantly reducing the
dissolved arsenic levels down-gradient of the trench.
Long-term performance issues (i.e., mineral precipitation and biofouling) observed at
other air sparging trenches were evaluated and solutions for such potential issues were
incorporated in the design. The air sparging trench alternative evaluation resulted in an
amendment of the original ROD with a substantial cost saving to the client.
Presenting Author: Omer J. Uppal
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